Mitsunobu Reagent [Triphenyl-phosphine(TPP) and Diethyl Azodi-carboxylate (DEAD)/Diisopropyl azodicarboxylate(DIAD)]
نویسندگان
چکیده
منابع مشابه
The Hendrickson reagent and the Mitsunobu reaction: a mechanistic study.
The alkoxytriphenylphosphonium ion intermediate of the Mitsunobu reaction can be generated using the Hendrickson reagent, triphenylphosphonium anhydride trifluoromethanesulfonate, 1. Strangely, while the reagent 1 can be used in place of the Mitsunobu reagents (triphenylphosphine and a dialkylazodicarboxylate) for the esterification of primary alcohols, secondary alcohols such as menthol underg...
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ژورنال
عنوان ژورنال: Synlett
سال: 2003
ISSN: 0936-5214,1437-2096
DOI: 10.1055/s-2003-39913